“…[ 10 ] FCDs basically consist of two conjugated line defects, the so‐called focal conics, lying in orthogonal planes, around which parallel smectic layers are wrapped. Using different internal structures and self‐organizations of FCDs that can be varied with anchoring conditions, periodic assemblies of FCDs were demonstrated to be scattering systems potentially suitable for display applications, [ 11–14 ] efficient superhydrophobic surfaces, [ 15 ] templates for fabricating microlens arrays, [ 16 ] optically selective photomasks, [ 17 ] matrices for organizing quantum dots, [ 18 ] and polarization‐dependent light diffraction gratings. [ 19 ] While advanced optical functions have been arising from SmA defect patterns owing to their internal ordering, assembly, and combination with guest optical nanomaterials, however, an outstanding issue that prevents from dynamically tuning the optics of these systems remains the structural irreversibility of SmA defect patterns with voltage.…”