Micro unmanned underwater vehicles
(UUVs) need to house propulsion mechanisms that are small in size
but sufficiently powerful to deliver on-demand acceleration for tight
radius turns, burst-driven docking maneuvers, and low-speed course
corrections. Recently, small-scale hydrogen peroxide (H2O2) propulsion mechanisms have shown great promise in
delivering pulsatile thrust for such acceleration needs. However,
the need for robust, high surface area nanocatalysts that can be manufactured
on a large scale for integration into micro UUV reaction chambers
is still needed. In this report, a thermal/electrical insulator, silicon
oxide (SiO2) microfibers, is used as a support for platinum
nanoparticle (PtNP) catalysts. The mercapto-silanization of the SiO2 microfibers enables
strong covalent attachment with PtNPs, and the resultant PtNP–SiO2 fibers act as a robust, high surface area catalyst for H2O2 decomposition. The PtNP–SiO2 catalysts are fitted inside a micro UUV reaction chamber for vehicular
propulsion; the catalysts can propel a micro UUV for 5.9 m at a velocity
of 1.18 m/s with 50 mL of 50% (w/w) H2O2. The
concomitance of facile fabrication, economic and scalable processing,
and high performanceincluding a reduction in H2O2 decomposition activation energy of 40–50% over
conventional material catalystspaves the way for using these
nanostructured microfibers in modern, small-scale underwater vehicle
propulsion systems.