LiHe$^+$ in the early Universe: a full assessment of its reaction network and final abundances

Abstract

We present the results of quantum calculations based on entirely ab initio methods for a variety of molecular processes and chemical reactions involving the LiHe + ionic polar molecule. With the aid of these calculations we derive accurate reaction rates and fitting expressions valid over a range of gas temperatures representative of the typical conditions of the pregalactic gas. With the help of a full chemical network, we then compute the evolution of the abundance of LiHe + as function of redshift in the early Universe. Finally, we compare the relative abundance of LiHe + with that of other polar cations formed in the same redshift interval.