The free central-limit theorem, a fundamental theorem in free probability, states that empirical averages of freely independent random variables are asymptotically semi-circular. We extend this theorem to general dynamical systems of operators that we define using a free random variable X and a group of *-automorphims describing the evolution of X. We introduce free mixing coefficients that measure how far a dynamical system is from being freely independent. Under conditions on those coefficients, we prove that the free central-limit theorem also holds for these processes and provide Berry-Essen bounds. We generalize this to triangular arrays and U-statistics. Finally we draw connections with classical probability and random matrix theory with a series of examples.