Good optical quality single crystals of pure and doped L-Alaninium Maleate (LAM) crystals have been grown. The crystals have been grown by slow evaporation method at a constant temperature of 35˚C from its aqueous solution. The grown single crystals of pure and doped LAM were characterized by employing FTIR, SHG, ICP, Dielectric study and X-ray diffraction methods.