2017
DOI: 10.1134/s1560090417060112
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Linear-Dendritic Block Copolymers Based on N-Isopropylacrylamide and Perfluorinated Polyphenylenegermane: Synthesis and Properties at Various Interfacial Boundaries

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Cited by 3 publications
(4 citation statements)
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“…The relative constant of chain transfer on bis -(pentafluorophenyl)germane during radical polymerization of NIPAAm equal to 2.2 determined previously using Mayo method indicates that if it is possible to use this polymer as a basis for production of block copolymers [ 22 ]. To obtain an amphiphilic linear block copolymer, a chain transfer reaction was used at the initial stage to obtain a functional polymer PNIPAAm–Ge(C 6 F 5 ) 2 H ( Scheme 1 ).…”
Section: Resultsmentioning
confidence: 99%
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“…The relative constant of chain transfer on bis -(pentafluorophenyl)germane during radical polymerization of NIPAAm equal to 2.2 determined previously using Mayo method indicates that if it is possible to use this polymer as a basis for production of block copolymers [ 22 ]. To obtain an amphiphilic linear block copolymer, a chain transfer reaction was used at the initial stage to obtain a functional polymer PNIPAAm–Ge(C 6 F 5 ) 2 H ( Scheme 1 ).…”
Section: Resultsmentioning
confidence: 99%
“…The surface pressure isotherms of the functional polymer PNIPAAm–Ge(C 6 F 5 ) 2 H using a mixture of solvents chloroform/methanol on subphases of different acidity and at different volumes of spreading solutions were obtained also. The curves were compared with similar curves obtained when chloroform was used as a solvent [ 22 ]. It was found that in the case of the functional polymer PNIPAAm–Ge(C 6 F 5 ) 2 H the presence of methanol in the mixture of the spreading solution does not have a significant effect on the behavior of macromolecules at the water–air interface, that is, only PFMA units participate in the formation of hydrogen bonds.…”
Section: Resultsmentioning
confidence: 99%
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