Silanes and Other Coupling Agents 2020
DOI: 10.1201/9780429070426-5
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Linking mechanical properties of silanes to their chemical structure: An analytical study of γ-GPS solutions and films

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“…Other studies report the positive effect of the heat treatment on the bond strength of ceramic cement and resin, 12 14 supported by improving crosslinking, preventing water penetration into the silane layer, 24 oligomerization via the connection of the glass matrix to the silane agent, 25 evaporation of solvent and residues from the hydrolysis of silanol, and finally, the formation of extensive gradients of internal pressure. 26 …”
Section: Discussionmentioning
confidence: 99%
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“…Other studies report the positive effect of the heat treatment on the bond strength of ceramic cement and resin, 12 14 supported by improving crosslinking, preventing water penetration into the silane layer, 24 oligomerization via the connection of the glass matrix to the silane agent, 25 evaporation of solvent and residues from the hydrolysis of silanol, and finally, the formation of extensive gradients of internal pressure. 26 …”
Section: Discussionmentioning
confidence: 99%
“…Knowing this, supported by the results of this study, it is suggested that the 60-second wait promotes sufficient solvent volatilization, without requiring the use of heated air. Other studies report the positive effect of the heat treatment on the bond strength of ceramic cement and resin, 12,14 supported by improving crosslinking, preventing water penetration into the silane layer, 24 oligomerization via the connection of the glass matrix to the silane agent, 25 evaporation of solvent and residues from the hydrolysis of silanol, and finally, the formation of extensive gradients of internal pressure. 26 This divergence of results on the effect of the heat treatment on bond strength may be due to differences in the type of silane, composition, solvents, and duration of hydrolysis in addition to the details of application such as air temperature, method, and duration of heating.…”
Section: Discussionmentioning
confidence: 99%