2006
DOI: 10.1029/2006gl026115
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Liquid CO2 venting on the seafloor: Yonaguni Knoll IV hydrothermal system, Okinawa Trough

Abstract: [1] We determined the chemical and isotopic compositions of the liquid CO 2 found on Yonaguni IV knoll hydrothermal site, as well as those in hydrothermal fluid venting from the surrounding chimneys. The d 13 C of both CO 2 and CH 4 in the liquid CO 2 almost coincide with those in the hydrothermal fluid, suggesting that the liquid CO 2 must be derived from the hydrothermal fluid. While showing homogeneous d 13 C, the hydrothermal fluids exhibit wide variation in gas contents. Active phase separation must be ta… Show more

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Cited by 108 publications
(136 citation statements)
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“…The Okinawa Trough is a backarc basin in the rifting to spreading stage characterized by the development of normal faulting of transitional crust (atypical crust with mantle-derived material) and frequent magma intrusions, which provides a favorable geological environment for the development of seafloor hydrothermal systems [8,41,42]. As of 2016, there were at least 15 deep-sea hydrothermal fields reported in the Okinawa Trough based on the InterRidge data base, including the Minami-Ensei (e.g., [10]), Iheya North [9,11,43], Jade [7,13], Hakurei [8], Hatoma [44][45][46], Yonaguni Knoll IV [12,14,47], and Tangyin hydrothermal fields [48,49]. The Iheya North knoll hydrothermal field (27 ∘ 47.2 N, 126 ∘ 53.9 E) is located at a water depth about 1,000 m along the eastern slope of a small knoll, part of the Iheya North knoll volcanic complex ( Figure 1; [8]).…”
Section: Geological Settingmentioning
confidence: 99%
See 1 more Smart Citation
“…The Okinawa Trough is a backarc basin in the rifting to spreading stage characterized by the development of normal faulting of transitional crust (atypical crust with mantle-derived material) and frequent magma intrusions, which provides a favorable geological environment for the development of seafloor hydrothermal systems [8,41,42]. As of 2016, there were at least 15 deep-sea hydrothermal fields reported in the Okinawa Trough based on the InterRidge data base, including the Minami-Ensei (e.g., [10]), Iheya North [9,11,43], Jade [7,13], Hakurei [8], Hatoma [44][45][46], Yonaguni Knoll IV [12,14,47], and Tangyin hydrothermal fields [48,49]. The Iheya North knoll hydrothermal field (27 ∘ 47.2 N, 126 ∘ 53.9 E) is located at a water depth about 1,000 m along the eastern slope of a small knoll, part of the Iheya North knoll volcanic complex ( Figure 1; [8]).…”
Section: Geological Settingmentioning
confidence: 99%
“…In the Okinawa Trough, the vent fluid chemistry of seafloor hydrothermal systems has been characterized by enrichment in CO 2 , CH 4 , NH 4 + , and K + compared with those in typical sediment-free midocean ridge (MOR) hydrothermal fluids (e.g., [6][7][8][9][10][11][12][13][14]). The high K + content (6.9-79.2 mmol kg −1 ) in the estimated source fluid is typical for the Iheya North knoll hydrothermal field due to hydrothermal reaction with K-enriched felsic rocks.…”
Section: Introductionmentioning
confidence: 99%
“…Observations during dive surveys indicate the elongated valley is covered mainly with muddy sediment, except for active hydrothermal sites, and that the northern slope of the valley has volcanic breccia . A diverse style of fluid emanations occurs within the Daiyon-Yonaguni Knoll hydrothermal field (Inagaki et al 2006;Konno et al 2006;Suzuki et al 2008). A large chimney-mound complex called the Tiger site, which is approximately 10-m high, is located near the boundary between the slope of the knoll and sediment seafloor at water depth of~1,370 m. Vigorous venting of blackish-smoky fluids up to 328 C has been recorded from the basal part of the mound complex, which seems to mark the central part of the present hydrothermal activity in the field.…”
Section: Daiyon-yonaguni Knoll Hydrothermal Fieldmentioning
confidence: 99%
“…Venting of clear fluid with the highest temperature of 220 C was observed at the foot of the mound, which was accompanied with discharge of significant amount of liquid CO 2 droplets. Liquid CO 2 emanation from altered sediment has been observed in many places around the active hydrothermal mounds (Inagaki et al 2006;Konno et al 2006). In the southern part of the hydrothermal field (the Abyss Vent site), diffusive fluid venting was observed from the seafloor which is covered with sediment associated whitish hydrothermal crusts (Inagaki et al 2006).…”
Section: Daiyon-yonaguni Knoll Hydrothermal Fieldmentioning
confidence: 99%
“…Subcritical phase separation produces a volatiledominant ''vapor phase'' and a volatile-stripped ''liquid phase,'' which differs from the solutecondensed ''brine phase'' produced by supercritical phase separation . Volatile stripping associated with subcritical phase separation would be accompanied by slight carbon isotope fractionation for CO 2 , as suggested by the observation at the Yonaguni IV hydrothermal field [Konno et al, 2006]. Thus, the slight Cl enrichment and strong CO 2 depletion without an altered 13 C CO2 in the post-drilling fluid are consistent with a ''liquid phase'' fluid from subcritical phase separation beneath the seafloor.…”
Section: à430mentioning
confidence: 69%