Liquid Crystal Entrapped Porous Films for Ammonia Sensing and Determination of Surface Properties of Liquid Crystal Molecule

Abstract

A highly ordered porous film was fabricated by the sol-gel process using 3-mercaptopropyltrimethoxysilane (MPTMS) precursor and polystyrene microspheres template. The liquid crystal (LC) (4-(Octyloxy) benzoic acid) (OBA) was entrapped into the voids of the pre-fabricated porous structure to obtain sensing materials that were characterized by scanning electron microscope (SEM) and fourier transform infrared spectroscopy (FT-IR). The impedance of the films was measured and the capacitive reactance response (1/-X) of LC-based sensor exhibited satisfactory linear correlation (R 2 = 0.9994) with the concentration of ammonia up to 50 ppm with a limit of detection (LOD) and quantification of 1.2 ppm and 4.0 ppm, respectively. The sensor exhibited high selectivity to ammonia compared to the different classes of solvent vapors, and satisfactory repeatability (RSD = 4 %) and response time (10 min). Also, inverse gas chromatography (IGC) was used to confirm the acidic surface behavior of LC and its selectivity to ammonia. The results proved that the studied LC-based sensor may be promise candidate for sensitive and selective determination of ammonia.

Surface Physicochemical Characterization of Shepherd’s Purse (Capsella bursa-pastoris) by Inverse Gas Chromatography

“…Then, to get rid of different pollutants and impurities, they were extensively cleaned with distilled water. At 383.2 K for 24 h, an oven was used to dry the completely washed plants (23,28). With a grinder, they were further ground to 80-100 mesh.…”

“…Several techniques, including pHpzc determination, zeta potential tests, and the Boehm titration method, can be used to determine the acidity or alkalinity of the material surface. The IGC approach, however, offers straightforward and quick findings and enables the evaluation of several surface properties in addition to acidity and alkalinity parameters (21)(22)(23).…”