Liquid + liquid equilibrium and thermodynamic modeling of water + cyclohexanone + ethyl acetate at different temperatures

Guo, Hongyue; Zhao, Yicong; Pang, Yufan; Li, Jun; Li, Qingsong

doi:10.1016/j.jct.2021.106617

Cited by 4 publications

(2 citation statements)

References 43 publications

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“…The injector and detector had a temperature of 493.15 K. The starting temperature in the oven was 423.15 K, which was maintained for 0.2 min before increasing to 493.15 K at a rate of 40 K·min –1 for 4.5 min. The sample analysis should be conducted at least three times to confirm that the error is less than 0.1% . Simultaneously, the standard uncertainty was determined using GUM and related recommendations. − …”

Section: Methodsmentioning

confidence: 99%

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Liquid–Liquid Equilibrium Measurement and Thermodynamic Modeling for the Ternary System of Water + Epichlorohydrin + Solvents (n-Propyl Acetate, 2-Ethyl-1-hexanol) at Different Temperatures

et al. 2023

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To separate and purify epichlorohydrin from water, the liquid–liquid equilibrium (LLE) data of water + epichlorohydrin + solvents (n-propyl acetate, 2-ethyl-1-hexanol) at 303.2, 313.2, and 323.2 K were measured at 101.3 kPa. The extraction ability of an extractant was evaluated using the distribution coefficient (D) and selectivity factor (S). Simultaneously, the Bachmann and Hand equations were used to verify the accuracy of the liquid–liquid equilibrium data. The NRTL and UNIQUAC models successfully correlated the LLE data, and the root mean square deviation for each model was less than 0.50%. Finally, GUI-MATLAB tools were employed to confirm that the regression parameters of the thermodynamic model areconsistent.

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Section: Methodsmentioning

confidence: 99%

“…The sample analysis should be conducted at least three times to confirm that the error is less than 0.1%. 23 Simultaneously, the standard uncertainty was determined using GUM and related recommendations. 24−26 2.3.…”

Section: Experimental Instruments and Techniquesmentioning

confidence: 99%