Liquid‐liquid extraction with association effects

Johnson, A. I.; Raal, J. David

doi:10.1002/cjce.5450440111

Can J Chem Eng

1966

DOI: 10.1002/cjce.5450440111

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Liquid‐liquid extraction with association effects

A. I. Johnson

J. David Raal

Abstract: Acetic and propionic acids were transferred from aqueous so1utior)s into n-heptyl alcohol, diisobutyl ketone, diisopropyl ether, and n-heptane in an extraction cell of the Lewis type. The experiments were conducted over wide

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1970

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Mass transfer and thermodynamic effects in emulsion polymerisation

Brooks

1970

Brit. Poly. J.

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The course of emulsion polymerisation is shown to depend on the water‐solubility of the monomers concerned. With insoluble monomers, the mass transfer rate of monomer to polymer particles can sometimes be exceeded by the polymerisation rate, and viscosity within the particles is appreciable throughout the course of the reaction. Thus, surfactant is adsorbed before monomer droplets disappear. With more soluble monomers, mass transfer rates of monomer are high and since the equilibrium concentration of polymer in particles is low the monomer droplets disappear early in the reaction. Consequently, water‐insoluble monomers often conform to Smith‐Ewart behaviour, whereas water‐soluble monomers do not. With water‐soluble monomers the final particle number is proportional to the cube of the initial surfactant concentration.

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Mass transfer and thermodynamic effects in emulsion polymerisation

Brooks

1970

Brit. Poly. J.

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Liquid‐liquid extraction with association effects

Abstract: Acetic and propionic acids were transferred from aqueous so1utior)s into n-heptyl alcohol, diisobutyl ketone, diisopropyl ether, and n-heptane in an extraction cell of the Lewis type. The experiments were conducted over wide

Cited by 1 publication

References 21 publications

Mass transfer and thermodynamic effects in emulsion polymerisation

Mass transfer and thermodynamic effects in emulsion polymerisation

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