Liquid-Vapor Equilibrium for the System: Perfluoro-n-hexane-n-Hexane¹

Phase behavior of carbon dioxide mixtures with n-alkanes and n-perfluoroalkanes

“…5 the liquid-liquid envelope for a mixture of n-C 7 H 16 + n-C 6 F 14 is also shown. We have also calculated the vapor-liquid phase behavior of the n-C 6 H 14 + n-C 6 F 14 mixture, and compare our results with the available experimental data [56] in Fig. 6.…”

“…Symbols represent the experimental data for C 6 H 14 + C 7 F 16 (᭹)[56] and C 6 H 14 + C 6 F 14( [60], ᭛[61], ᮀ[56]). The theoretical predictions are shown by the continuous curves.…”

“…Symbols represent the experimental data of Dunlap et al[56]: (᭺) 318 K, (ᮀ) 308 K and ( ) 298 K. The theoretical predictions are shown by the continuous curves.…”

“…(b) Vapor-liquid equilibrium for the n-hexane + n-perfluorohexane and n-hexane + n-perfluoroheptane binary mixtures compared with the SAFT-VR predictions. Symbols represent the experimental data of Dunlap et al[56] at 298.15 K (᭺) for C 6 H 14 + C 6 F 14 and Duce et al[57] at 303.15 K ( * ) for C 6 H 14 + C 7 F 16 .…”

Modelling the phase behaviour and excess properties of alkane + perfluoroalkane binary mixtures with the SAFT–VR approach

“…Vapour-liquid equilibria for the n-C 6 H 14 + n-C 6 F 14 system. The diamonds, triangles and squares represent respectively the experimental data at 25, 35 and 45 • C, from [28]. The lines correspond to the SAFT-VR predictions with 12 = 0.840 and γ 12 = 1.045.…”