2021
DOI: 10.1016/j.electacta.2021.137914
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Lithiated Nafion plasticised by a mixture of ethylene carbonate and sulfolane

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Cited by 17 publications
(11 citation statements)
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“…Reproduced with permission. [ 127 ] Copyright 2021, Elsevier. c) Temperature dependence of the ionic conductivity of the SICPEs with the polysiloxane‐based ionomer including lithium tetraphenyl borate and cyclic carbonate as randomly placed side chains (LiPSBC) for different fractions of the PEG600 plasticizer.…”
Section: Strategies To Increase the Ionic Conductivity Of Sicpesmentioning
confidence: 99%
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“…Reproduced with permission. [ 127 ] Copyright 2021, Elsevier. c) Temperature dependence of the ionic conductivity of the SICPEs with the polysiloxane‐based ionomer including lithium tetraphenyl borate and cyclic carbonate as randomly placed side chains (LiPSBC) for different fractions of the PEG600 plasticizer.…”
Section: Strategies To Increase the Ionic Conductivity Of Sicpesmentioning
confidence: 99%
“…Sanginov et al. [ 127 ] introduced a sulfolane (SL) solvent with a high boiling point and a low vapor pressure as well as EC into Li‐Nafion‐based SICPEs. The quantum‐chemical calculation showed a thermodynamically stable coordination structure for Li + with a flat triangular configuration in the first solvation shell, as shown in Figure a.…”
Section: Strategies To Increase the Ionic Conductivity Of Sicpesmentioning
confidence: 99%
See 1 more Smart Citation
“…To assess the thermodynamic stability of the studied complexes of solvated ionic particles, incremental (stepwise) values of the formation energies (∆ f G o inc ) were considered as the Gibbs energy of the reaction of the sequential attachment of the solvent molecule to complexes [67], based on the second consequence of Hess's law.…”
Section: Quantum Chemical Calculationsmentioning
confidence: 99%
“…In this paper, we investigate a 1 m solution of LiBF 4 in two binary solvent mixtures: EC/DMC (1:1) and SL/DMC (1:1). Earlier [67], we proposed an algorithm for the theoretical evaluation of the electrochemical stability of lithium-conducting electrolytes based on a mixed solvent. In this paper, this algorithm is used to analyse the effect of the nature of solvents on the redox potential of the electrolyte.…”
Section: Introductionmentioning
confidence: 99%