Lithium Dendrite Growth Suppression and Ionic Conductivity of Li2S-P2S5-P2O5 Glass Solid Electrolytes Prepared by Mechanical Milling

Cengiz, Mazlum; Oh, Hyukkeun; Lee, Se-Hee

doi:10.1149/2.0311916jes

Cited by 21 publications

(17 citation statements)

References 47 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The last is followed by a cooling step, either slow cooling (to ensure crystallization) or quenching step in ice water (to obtain amorphous material). [157,163] In the mechanochemical method, glass, glass-ceramic, and ceramic sulfides are typically synthesized under nonequilibrium conditions using a high-energy planetary ball mill apparatus at room temperature, [150,156,223] which obviates the need for high temperatures and cooling steps. Explicit guidelines and ball-milling parameters (material and geometry of the ball milling jar and balls, rotation speed, milling cycling program, the respective volumetric/ weight ration of the milling jar, balls, and the powders) [224] can be widely found in the literature.…”

Section: Sulfidesmentioning

confidence: 99%

Solid‐State Li–Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces

Kim

Balaish

Wadaguchi

et al. 2020

Advanced Energy Materials

445

355

View full text Add to dashboard Cite

lightweight, and compact and allow for versatile device geometries. They must also be scalable and offer high energy density to provide improved packing efficiency and longer device operation. Although both Ni-MH batteries and LIBs have been commercialized since the 1990s, [1] LIBs possess twice the gravimetric/volumetric energy density (250 Wh kg −1 /700 Wh L −1 vs 170 Wh kg −1 /350 Wh L −1 ), [2] higher battery voltage (3.7 V vs 1.2 V), and longer cycle life with lower self-discharge, [3] contributing tremendously to the proliferation of portable electronic devices (e.g., mobile phones, laptops, cameras, tablets) as well as emerging new technologies such as wearable electronic devices (e.g., smart watches and sport-related tracking devices). Their high gravimetric/ volumetric energy density, [2] excellent cycle life (thousands of cycles), and lack of the memory effect have positioned LIBs as state-of-the-art power sources and one of the greatest successes of modern electrochemistry, revolutionizing the way we acquire, process, transmit, and share information globally. Nevertheless, advances in battery energy density, safety, costs, and flexibility in shape and size are still needed to keep up with the rapidly growing demand for devices with even longer runtime as well as real-time data collection and transmission capabilities in addition to increasingly energy-demanding applications such as electric vehicles (EVs) and electricity grid storage. Even though LIBs were first commercialized in all electric vehicles (EVs) in 2010 and also emerged for grid application in the same time frame, the low energy density (≈250 Wh kg −1 ) and high average cost (≈$156 kWh −1 in 2019) of conventional LIBs do not meet the requirements for advanced EVs and grid-scale energy storage. [4][5][6] Specifically, the driving range per charge (miles), which is related to the energy density of each cell, and the cost are important parameters for EVs. For example, one 85 kWh battery pack in a Tesla Model S requires 7104 LIB cells, with an energy density of 265 Wh kg −1 , providing an average range of 250 miles, which is ahead of the range of other EVs but still behind the target of 375 miles. [4] In grid-scale applications, LIBs can be used for various tasks: frequency regulation, peak shaving, load leveling, and large-scale integration of renewable energies, with specific properties generally required for each task. For frequency regulation, LIBs need to provide a fast response, high rate performance, and high-power capability,The introduction of new, safe, and reliable solid-electrolyte chemistries and technologies can potentially overcome the challenges facing their liquid counterparts while widening the breadth of possible applications. Through tech-historic evolution and rationally analyzing the transition from liquidbased Li-ion batteries (LIBs) to all-solid-state Li-metal batteries (ASSLBs), a roadmap for the development of a successful oxide and sulfide-based ASSLB focusing on interfacial challenges is introduced, while accounting ...

show abstract

Section: Sulfidesmentioning

confidence: 99%

Solid‐State Li–Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces

Kim

Balaish

Wadaguchi

et al. 2020

Advanced Energy Materials

445

355

View full text Add to dashboard Cite

show abstract

“…Inspired by the fabrication of amorphous solid conductor for LIBs, such as Li 3 PO 4 , Su and Tsuruoka proposed a plasmaassisted atomic layer deposition method to fabricate amorphous oxygen-deficient Mg 2.4 P 2 O 5.4 thin film in 2019 (Cengiz et al, 2019;Su et al, 2019). It exhibited an ionic conductivity of 1.6 × 10 −7 S cm −1 at 500 • C. The hopping conduction of Mg ions in the disordered amorphous phosphate matrix was believed to result in the conductivity.…”

Section: Phosphates-based Mg Ion Solid Conductorsmentioning

confidence: 99%

“…The technical challenge of Li anode comes from the lithium dendrite formed on surface during cycling, which could penetrate the separator and result in the short-circuit of the battery and thus fire-catching or even explosion (Janek and Zeier, 2016;Chen et al, 2020). Despite the endeavors to suppress the dendrite formation, the progress is limited and none of the solutions meets the commercial standards (Cengiz et al, 2019;Michel et al, 2019). Therefore, next generation advanced rechargeable batteries, such as multivalent metal (Mg, Ca, Al etc.…”

Section: Introductionmentioning

confidence: 99%

Recent Development of Mg Ion Solid Electrolyte

et al. 2020

View full text Add to dashboard Cite

Although the successful deployment of lithium-ion batteries (LIBs) in various fields such as consumer electronics, electric vehicles and electric grid, the efforts are still ongoing to pursue the next-generation battery systems with higher energy densities. Interest has been increasing in the batteries relying on the multivalent-ions such as Mg 2+ , Zn 2+ , and Al 3+ , because of the higher volumetric energy densities than those of monovalent-ion batteries including LIBs and Na-ion batteries. Among them, magnesium batteries have attracted much attention due to the promising characteristics of Mg anode: a low redox potential (−2.356 V vs. SHE), a high volumetric energy density (3,833 mAh cm −3), atmospheric stability and the earth-abundance. However, the development of Mg batteries has progressed little since the first Mg-ion rechargeable battery was reported in 2000. A severe technological bottleneck concerns the organic electrolytes, which have limited compatibility with Mg anode and form an Mg-ion insulating passivation layer on the anode surface. Consequently, beneficial to the good chemical and mechanical stability, Mg-ion solid electrolyte should be a promising alternative to the liquid electrolyte. Herein, a mini review is presented to focus on the recent development of Mg-ion solid conductor. The performances and the limitations were also discussed in the review. We hope that the mini review could provide a quick grasp of the challenges in the area and inspire researchers to develop applicable solid electrolyte candidates for Mg batteries.

show abstract

“…All-solid-state batteries (ASSBs) have emerged as promising next-generation batteries because of their potential to provide high energy density and enhanced safety. − Utilization of Li metal as the anode in ASSBs is the ideal choice. However, challenges remain with regard to the stability of the Li metal anode, such as dendrite formation and large volume changes during cycling, which result in mechanical degradation at the interface between the anode and solid-state electrolyte (SSE). − This degradation not only contributes to a significant reduction of cell life but also leads to potential cell internal short circuits. − Strategies have been developed to analyze and resolve the interface issues caused by Li metal anode, such as adding a self-healing component into the SSE, softening the SSE with polymers, engineering of interlayers, and rational control of Li metal deposition based on theoretical studies. ,,,− …”

mentioning

confidence: 99%

“…Graphite, which is cheap and abundant, has demonstrated long cyclability with little volume change in all-solid-state Li-ion batteries. ,,− After lithiation, the product LiC 6 is thermodynamically stable with Li metal and has both electronic and ionic conductivity. Moreover, LiC 6 is shown to be lithiophilic and can facilitate Li metal deposition. ,, These properties suggest graphite can fit the aforementioned design requirements as a material for 3D anode networks in ASSBs.…”

mentioning

confidence: 99%

Graphite-Based Lithium-Free 3D Hybrid Anodes for High Energy Density All-Solid-State Batteries

Xing

Wang

et al. 2021

ACS Energy Lett.

View full text Add to dashboard Cite

All-solid-state lithium batteries often suffer from dendrite-driven shorting. Here, a lithium-free 3D anode design is reported to help address this challenge. Upon controlling the graphite anode and lithium metal oxide cathode capacity ratio, lithium metal deposition is intentionally induced in the pores formed by the 3D framework of the graphite and lithium thiophosphate-based solid electrolyte. By facilitating lithium deposition away from the interface between the anode composite and the solid-state electrolyte layer, this designed electrode can significantly mitigate the short-circuit problem in the battery. The 3D anode design demonstrates a 3-fold increase in critical current density over a planar lithium metal electrode when evaluated in a symmetric cell. Moreover, the lithium-free all-solid-state battery with a 3D anode and a LiNi0.85Co0.10Al0.05O2 (NCA) cathode also exhibits highly improved cycle life and Coulombic efficiency compared to the baseline cells. This electrode design provides a promising approach toward a high energy density, long life, and low-cost technology.

show abstract

Lithium Dendrite Growth Suppression and Ionic Conductivity of Li₂S-P₂S₅-P₂O₅ Glass Solid Electrolytes Prepared by Mechanical Milling

Cited by 21 publications

References 47 publications

Solid‐State Li–Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces

Solid‐State Li–Metal Batteries: Challenges and Horizons of Oxide and Sulfide Solid Electrolytes and Their Interfaces

Recent Development of Mg Ion Solid Electrolyte

Graphite-Based Lithium-Free 3D Hybrid Anodes for High Energy Density All-Solid-State Batteries

Contact Info

Product

Resources

About