Lithium Salts of N,N'-Disubstituted Pentanesulfinamidines as Promising Additives for Lithium Power Sources

Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides

“…Ferry reported the use of dialkylaminosulfur trifluorides, amines, and trifluoro­methyl­trimethyl­silane for a specific synthesis of trifluoromethyl-substituted sulfinamidines (Scheme c) . In spite of their application as ligands, synthetic intermediates, and additives for lithium power sources, ,, no relevant advances have been reported during the past decades for a general synthesis of sulfinamidines. Furthermore, the preparation and chemistry of sulfinimidate esters remains still severely underdeveloped.…”