Samples with the nominal composition Bi,Sr,Ca, -,Li,Cu,O, (x = 0.2,0.4, and 0.6) and Bi,Sr,CaCu, -~ . Li,O, (x = 0.4,0.6, and 1.0) were prepared by the solid state reaction method. The role of Li at both Caand Cu sites in the Bi-2212 composition were studied. From the X-ray diffraction data it was found that the Li-doped at the Ca site increases the c-axis and that doped at the Cu site decreases the c-axis.From the D.C. four-probe resistivity data it was found that Li-doped at the Ca site reduces the T, and the Li-doped at the Cu site gives TJO) above the liquid nitrogen temperature. It was observed that the Li doping reduces the melting point of Bi-2212 composition. The presence of Lithium was confirmed by inductive the coupled plasma method.