2020
DOI: 10.1016/j.sedgeo.2020.105717
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Lithological correction of chemical weathering proxies based on K, Rb, and Mg contents for isolation of orbital signals in clastic sedimentary archives

Abstract: This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. This version will undergo additional copyediting, typesetting and review before it is published in its final form, but we are providing this version to give early visibility of the article. Please note that, during the production process, errors may be discovered which could affect the content, a… Show more

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Cited by 10 publications
(6 citation statements)
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“…It can be clearly seen that the lowest VWI values could be detected at the sediment base of the clayey loam between 102.6 and 102.8 m a.s.l. This is clear evidence of weathering and thus soil formation, which is also validated by the K 2 O/Rb 2 O ratio because there is greater retention and thus slower release of heavier alkali metal ions (Rb + ) from clay minerals compared to the lighter alkali metal ion (K + ) (Bosq et al, 2020;Matys Grygar et al, 2020). In comparison to Na and Ca, a possible resorption of K to clay minerals and its stronger binding through sorptive complexes in the soil are considered to be more likely.…”
Section: Late Weichselian-holocene Transitionmentioning
confidence: 79%
“…It can be clearly seen that the lowest VWI values could be detected at the sediment base of the clayey loam between 102.6 and 102.8 m a.s.l. This is clear evidence of weathering and thus soil formation, which is also validated by the K 2 O/Rb 2 O ratio because there is greater retention and thus slower release of heavier alkali metal ions (Rb + ) from clay minerals compared to the lighter alkali metal ion (K + ) (Bosq et al, 2020;Matys Grygar et al, 2020). In comparison to Na and Ca, a possible resorption of K to clay minerals and its stronger binding through sorptive complexes in the soil are considered to be more likely.…”
Section: Late Weichselian-holocene Transitionmentioning
confidence: 79%
“…There can be found also a full description of sediment geochemistry data processing. Two geochemical parameters were evaluated: K/Rb as a proxy for chemical weathering intensity (Matys Grygar et al, 2020) and Pb/Si as a quantitative measure of anthropogenic contamination since the 20th century ce (Matys Grygar et al, 2013). Deviations of the K/Rb and Pb/Si ratios from average behaviour were evaluated as exponential forms of the robust regression residuals (denoted as RRes in figures).…”
Section: Methodsmentioning
confidence: 99%
“…There can be found also a full description of sediment geochemistry data processing. Two geochemical parameters were evaluated: K/Rb as a proxy for chemical weathering intensity (Matys Grygar et al, 2020) and Pb/Si as a quantitative measure of anthropogenic contamination since the 20th century CE (Matys Grygar et al, 2013)…”
Section: Geochemical Data Processingmentioning
confidence: 99%
“…There are four main types of data series that are used to analyse the presence of Milankovitch cycles from sedimentary records. The first category is a physical property of the rocks, such as colour, particle size and bedding rhythms (Grygar et al ., 2020; Ma & Li, 2020). The second category is geochemical data, such as Fe or Al elemental content, CaCO 3 mass fraction, major element content, trace element content, or elemental ratios (Meyers & Sageman, 2007; Li et al ., 2018; Cheng et al ., 2020).…”
Section: Methodsmentioning
confidence: 99%