In this work, we consider the multi-wall braneworld arisen from multiscalar fields, and investigate the localization and resonances of spin-1/2 fermion on the multi-walls. We build two analytic multi-wall solutions with a polynomial superpotential and a modified sine-Gordon superpotential respectively. The massless fermion is the only bound state and localized between the two outermost sub-branes. The factors affecting the number of massive resonant fermions are analyzed. What interesting is that all the fermion resonant states are non-degenerate for the cases of single-and two-walls, however, doubly-degenerate fermion resonant states emerge for the cases of three-and four-walls. This novel phenomenon could be potentially interesting in phenomenology.