Nano Online 2016
DOI: 10.1515/nano.11671_2015.56
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Localized Surface Plasmon Resonance of Silver Nanotriangles Synthesized by a Versatile Solution Reaction

Abstract: The surface plasmon resonance (SPR) of silver nanoparticles can be tuned throughout the visible and near-infrared region by their shape and size. Considering SPR applications, an easy and controllable method for preparing the silver nanocrystals with defined shape and size, is necessary. In this work, the triangular silver nanoplates were synthesized by reducing Ag + ions with ascorbic acid in the presence of silver seeds and poly(vinylpyrrolidone) (PVP) at room temperature. Both the seeds (as the nucleation s… Show more

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Cited by 3 publications
(5 citation statements)
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“…In particular, AuNP ranging in diameter from 5 to 40 nm has been widely used to enhance the response of SPR sensors [ 35 ]. Among all metal nanoparticles, gold and silver nanoparticles are particularly interesting because they have the strongest plasmonic interaction with light [ 36 ]. The signal enhancement by employing AuNP can be caused by different factors such as surface mass increasement due to AuNP and more molecules being attached to the AuNP than the planar gold surface; refractive index change by the particles; or electromagnetic field coupling between SPR and LSPR [ 37 ].…”
Section: Resultsmentioning
confidence: 99%
“…In particular, AuNP ranging in diameter from 5 to 40 nm has been widely used to enhance the response of SPR sensors [ 35 ]. Among all metal nanoparticles, gold and silver nanoparticles are particularly interesting because they have the strongest plasmonic interaction with light [ 36 ]. The signal enhancement by employing AuNP can be caused by different factors such as surface mass increasement due to AuNP and more molecules being attached to the AuNP than the planar gold surface; refractive index change by the particles; or electromagnetic field coupling between SPR and LSPR [ 37 ].…”
Section: Resultsmentioning
confidence: 99%
“…It is reported that silver nanotriangle shows three absorption peaks corresponding to three different modes of plasmon oscillation such as in-plane dipole resonance, in-plane quadrupole plasmon resonance and out-of-plane quadrupole resonance [40]. The position of the band around 560 nm and strong band around 420 nm, respectively, due to in-plane dipole resonance and in-plane quadrupole plasmon resonance, are not fixed and these peaks get red-shifted with the increase in the edge length of the nanotriangle [41][42][43]. However, there is a fixed band at around 350 nm, which does not change with the change in the edge length.…”
Section: Uv/vis Spectroscopy Analysismentioning
confidence: 99%
“…As matter of fact, the scattering cross-section of silver is greater than that of the other kinds of metals. Compared to other shapes, the anisotropic morphology of nanotriangles offers multiple LSPR bands with their decreased symmetry [158]. Triangular nanoplates offer optical extinction peaks resulting from in-plane and out-of-plane modes, which can be conveniently tuned by controlling their aspect ratio (the ratio of edge length to thickness) [158,159].…”
Section: Investigation Into Contrast Enhancement Using Silica-coated Silver Nanoplatesmentioning
confidence: 99%
“…Compared to other shapes, the anisotropic morphology of nanotriangles offers multiple LSPR bands with their decreased symmetry [158]. Triangular nanoplates offer optical extinction peaks resulting from in-plane and out-of-plane modes, which can be conveniently tuned by controlling their aspect ratio (the ratio of edge length to thickness) [158,159]. Since most of the signals are generated from tip area, nanotriangles provides excellent enhancement of the local field and the spatial resolution.…”
Section: Investigation Into Contrast Enhancement Using Silica-coated Silver Nanoplatesmentioning
confidence: 99%
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