2019
DOI: 10.1039/c8ce01795f
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Lone pair⋯π interaction versus σ-hole appearance in metal-bonded halogens

Abstract: Three complexes of N-(2,5-diluorophenyl)-2-pyrazine carboxamide and ZnX2 have been synthesized. The crystal structures reveal that in all three coordination compounds, metal-bound halides have interacted with π systems through a negative electrostatic region.

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Cited by 4 publications
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