Long cycle‐life aqueous Zn battery enabled by facile carbon nanotube coating on Cu current collector

Abstract

As an alternative to Li‐ion batteries, aqueous Zn batteries have gained attention due to the abundance of Zn metal, low reduction potential (–0.76 V vs. standard hydrogen electrode), and high theoretical capacity (820 mAh g–1) of multivalent Zn2+ ion. However, the growth of Zn dendrites and the formation of irreversible surface reaction byproducts pose challenges for ensuring a long battery lifespan and commercialization. Herein, the Cu foil coated with a single‐walled carbon nanotube (SWCNT) layer using a facile doctor blade casting method is utilized. The SWCNT‐coated Cu foil demonstrates a significantly longer battery lifespan compared to the bare Cu in the half‐cell tests. Through operando optical microscopy imaging, we are able to provide intuitive evidence that Zn deposition occurs between the carbon nanotube (CNT) coating and Cu substrate, in agreement with the computational results. Also, with various imaging techniques, the flat morphology and homogeneous distribution of Zn beneath the SWCNT layer are demonstrated. In addition, the full‐cell using CNT‐coated Cu exhibits a long cycle life compared to the control group, thereby demonstrating improved electrochemical performance with limited Zn for the cycling process.

Construction of an n-Type Fluorinated ZnO Interfacial Phase for a Stable Anode of Aqueous Zinc-Ion Batteries

“…However, the zinc metal anode of aqueous zinc-ion batteries usually suffers from uncontrollable zinc dendrites and harmful side reactions in practical applications. , The uneven zinc nucleation behavior will lead to the continuous accumulation of dendrites on the anode surface, which seriously reduces the life of zinc-ion batteries . In addition, pure zinc anodes will undergo hydrogen evolution and corrosion in weak acid electrolytes, and the generated basic zinc sulfate byproducts will further reduce the utilization efficiency of metal anodes. − Hence, optimizing the metal anode has become a crucial factor in promoting the development of zinc-ion batteries.…”