Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes

Lu, Yuanzhe; Zhu, Yuanqin; Zhong, Linfeng; Yu, Dingshan

doi:10.1016/j.cjsc.2024.100249

Chinese Journal of Structural Chemistry

2024

DOI: 10.1016/j.cjsc.2024.100249

|View full text |Cite

Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes

Yuanzhe Lu,

Yuanqin Zhu,

Linfeng Zhong

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

References 32 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Engineering π‐Electron Bridge Enables Low‐Potential 2D Redox Polymer Anodes for High‐Voltage Aqueous All‐Organic Batteries

Zhong,

Liu,

Zhang

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

Here, we propose a novel π‐electron bridge engineering strategy to explore a class of dioxin‐bridged 2D redox covalent organic polymer (RCOP) as trade‐off‐breaking anodes for high‐voltage aqueous all‐organic batteries (AAOBs). By establishing a tunable RCOP platform, we perform theoretical study to scrutinize how bridge units between active sites affect the electrode potential and redox activity for the first time. We discover that compared to common pyrazine bridge, the weakened conjugation and strong electron donor character of the proposed dioxin bridge can induce elevated LUMO level and enriched π‐electron populations in active sites, heralding a low electrode potential and enhanced redox activity. Besides, nonaromaticity induced molecular flexibility of dioxin bridge mitigates intermolecular stacking for sufficient active site exposure and charge carrier uptake. To experimentally corroborate this, a new dioxin‐bridged RCOP (D‐HATN) and its pyrazine‐bridged analogue (P‐HATN) are synthesized for proof‐of‐concept demonstration. Hence, D‐HATN displays excellent compatibility with Na+/Zn2+/NH4+/H3O+ and obviously lower redox potentials in various electrolytes compared to P‐HATN, while affording rapid Grotthuss‐type proton conduction and unprecedented durability in acid. Thus, the D‐HATN‐involved all‐organic proton battery delivers an average output voltage of 0.75 V, which can be further elevated to 1.63 V with alkaline‐acidic hybrid electrolyte design, affording markedly‐increased specific energy.

show abstract

Engineering π‐Electron Bridge Enables Low‐Potential 2D Redox Polymer Anodes for High‐Voltage Aqueous All‐Organic Batteries

Zhong,

Liu,

Zhang

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Engineering π‐Electron Bridge Enables Low‐Potential 2D Redox Polymer Anodes for High‐Voltage Aqueous All‐Organic Batteries

Zhong,

Liu,

Zhang

et al. 2024

Angew Chem Int Ed

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes

Cited by 2 publications

References 32 publications

Engineering π‐Electron Bridge Enables Low‐Potential 2D Redox Polymer Anodes for High‐Voltage Aqueous All‐Organic Batteries

Engineering π‐Electron Bridge Enables Low‐Potential 2D Redox Polymer Anodes for High‐Voltage Aqueous All‐Organic Batteries

Engineering π‐Electron Bridge Enables Low‐Potential 2D Redox Polymer Anodes for High‐Voltage Aqueous All‐Organic Batteries

Contact Info

Product

Resources

About