Long-lived oscillations in the chlorite-iodide-malonic acid reaction in batch

Inorganic reactions of iodine(III) in acidic solutions and free energy of iodous acid formation

“…Reaction (A) is of environmental interest in the evaluation of the consequences of a nuclear reactor accident 1–4 and in oceanic studies 5–8 and is part of several chemical oscillators, the Bray–Liebhafsky reaction 9–15, the Briggs–Rauscher reaction 9,16–22, and oscillators derived from the chlorite–iodide reaction 23–26 and from iodate reactions with reducing agents 27–32. Its mechanism depends on the experimental conditions and is not completely elucidated despite a large number of kinetic studies 33–36.…”

Inorganic reactions of iodine(+1) in acidic solutions

“…The reactions of iodine in the +1 oxidation state are of environmental interest in the evaluation of the consequences of a nuclear reactor accident 1–4, in oceanic studies 5–8, and are part of several chemical oscillators, the Bray–Liebhafsky reaction 9–15, the Briggs–Raucher reaction 10, 16–21, and the family of oscillators derived from the chlorite–iodide reaction 22–27. The formation of I(+1) and its disproportionation have been the subject of many works since about a century and we present a detailed analysis of the published data leading to a selection of the thermodynamic and kinetic constants' values.…”

The Kinetics and Mechanism of the Chlorine Dioxide−Iodide Ion Reaction

“…The redox reaction between chlorine dioxide and iodide ion has been the subject of intense studies for decades. − This reaction serves as a basis for the iodometric determination of ClO 2 . It is also an important subset in a series of oxychlorine-based exotic reactive systems. ,, …”