Long-lived solid state perchlorate ion selective sensor based on doped poly(3,4-ethylenedioxythiophene) (PEDOT) films

The Electrochemical Degradation of Poly(3,4-ethylenedioxythiophene) Films Electrodeposited from Aqueous Solutions

“…For instance, many studies have demonstrated that overoxidized polypyrrole films exhibit molecular-sieve properties, and such films have been used to fabricate glucose, alcohol, hydrazine, and dopamine sensors [29,[32][33][34][35][36]. (Over)oxidized PEDOT films were successfully used for sensing perchlorate [37]. According to [38] overoxidized poly (3,4-ethylenedioxythiophene) film-modified screen-printed carbon electrodes exhibited superior sensitivity and selectivity to dopamine.…”

Structural changes during the overoxidation of electrochemically deposited poly(3,4-ethylenedioxythiophene) films

“…For instance, many studies have demonstrated that overoxidized polypyrrole films exhibit molecular-sieve properties, and such films have been used to fabricate glucose, alcohol, hydrazine, and dopamine sensors [25][26][27][28][29][30][31][32]. (Over)oxidized PEDOT films were successfully used for sensing perchlorate [33]. According to [34] overoxidized poly(3,4-ethylenedioxythiophene) film-modified screen-printed carbon electrodes exhibited superior sensitivity and selectivity to dopamine.…”

Construction of a novel highly selective potentiometric perchlorate sensor based on neocuproine–Cu(II) complex formed in situ during the conditioning period

“…Until now, a number of perchlorate-selective potentiometric electrodes have been reported which were prepared based on various ionophore substances such as long chain quaternary ammonium ions [24][25][26], protonated dyes as bulky counter-ions [26,27], perchlorate ion-pair complexes with cations [28], metallic organic complexes [29][30][31][32][33][34], neutral carriers [35][36][37][38][39], anion exchange resins [39], conducting polymers [40,41], surfactant modified zeolits [42], chemically modified silica gel [43] and uranyl complexes [44]. Moreover, perchlorate selective electrodes reported in most of these studies lack of adequate potentiometric characteristics such as selectivity, sensitivity, response time, linear working range, life span, and detection limit.…”