To investigate transport and partitioning processes of
HgT in the Fox River, we coupled detailed time series
data
of total mercury (HgT) at the river mouth with
transect
sampling in the Lower Fox River. Unfiltered HgT
concentrations
in the Fox River during the study period (April 1994−October 1995) ranged from 1.8 to 182 ng L-1
with a median
of 24.8 ng L-1, predominantly (93.6%) in the
particulate
phase. These levels were significantly elevated
compared
with other large tributaries to Lake Michigan (Hurley, J.
P.; Shafer, M. M.; Cowell, S. E.; Overdier, J. T.; Hughes,
P.
E.; Armstrong, D. E. Environ. Sci. Technol.
1996,
30, 2093−2098). Transect sampling revealed progressively
increasing
water column HgT concentrations and HgT
particulate
enrichment downstream, which were consistent with trends
in sediment HgT levels in the river. Resuspended
sediments
are likely the predominant source of Hg from the Fox River
into Green Bay. Despite elevated HgT
concentrations,
methyl mercury (MeHg) concentrations were relatively low,
suggesting limited bioavailability of HgT associated
with
sediments.