PbC1,,Br,o-,, single crystals for various compositions were studied by Raman spectroscopy at 14 K. It is shown that the phonons are of one or two-mode behaviour wben the proportion x varies from 0 to 1. Lattice dynamic and group theory considerations related to structural data allow one to establish a mecbanism for the substitutional filling of tbe anion sites and tbeir participation in the lattice vibrations, the frequency of which has been measured as a function of x at 14 K. The maximum disorder given by the Raman line widths occurs for x = 0.25 and x = 0.75, in accordance with dielectric measurements.