The electromagnetic properties of an isotropic medium are the same in all directions. Accordingly, isotropic media are characterized simply by scalar constitutive parameters which relate the induction field phasors and to the primitive field phasors and . In contrast, anisotropic media exhibit directionally dependent electromagnetic properties, such that is not aligned with and/or is not aligned with . Furthermore, recent advances have focused attention on bianisotropic media, wherein both and are anisotropically coupled to both and . Therefore, dyadics (i.e., second‐rank Cartesian tensors) are needed to relate the primitive and the induction field phasors in both anisotropic and bianisotropic media. Correspondingly, these media exhibit a vastly more diverse range of phenomena than do isotropic media. A consequence of this wealth of interesting properties is that electromagnetic analyses are considerably more complicated for anisotropic and bianisotropic media than for isotropic media. In this chapter, anisotropic and bianisotropic media are discussed in terms of their constitutive dyadics and space–time symmetries. Planewave propagation, dyadic Green functions, and the conceptualization of anisotropic and bianisotropic media via homogenization are described. A brief account of anisotropic and bianisotropic behavior in nonlinear media concludes this chapter.