Outdoor light at night (LAN) would be a public concern potentially associated with adverse health outcomes mainly in developed countries, but it might also be an environmental health issue in developing countries. However, there have been few studies reporting the spatial and temporal aspects of LAN level changes incorporated with population exposure in such nations. Therefore, we analyzed the spatiotemporal patterns of outdoor LAN exposure changes across the Republic of Korea (ROK), a developing country in Asia, between 1995 and 2010. In addition, we incorporated the population and its demographic characteristics of light exposure in this research. We utilized Defense Meteorological Satellite Program (DMSP) Operational Linescan System (OLS) observations as a spatial proxy of LAN and the ROK census data. This research observed 57.6% (≈57,800 km 2 ) of land areas in the country to experience increases in outdoor artificial illumination at nights. The highest levels of LAN were found to affect about 58% of the total ROK population with major impacts on young and middle-aged people in recent years. Taking this research into account, it would require taking appropriate measures in controlling and abating outdoor artificial lights at night for both developing and developed countries. We anticipate that those efforts could prevent adverse health outcomes, for example, female breast cancer, potentially associated with LAN exposure.