Löslichkeit von Gasen in organischen Lösungsmitteln

Solubility of Syngas Components in Water, Acetic Acid, and Alcohol Using New Standard Fugacity Methodology

“…For the solubilities of H 2 in CH 3 COOH above 1 atm the only study available is Jónasson at all . The experimental points from this source are, however, not in agreement with the data sets at atmospheric pressure listed in the two other sources found: Maxted and Moon and Just . Due to the impossibility to confirm the exactness of Jónasson et al’s results, the system H 2 –CH 3 COOH was not included in the data regression.…”

“…41 The experimental points from this source are, however, not in agreement with the data sets at atmospheric pressure listed in the two other sources found: Maxted and Moon 42 and Just. 43 Due to the impossibility to confirm the exactness of Jońasson et al's results, the system H 2 −CH 3 COOH was not included in the data regression. For reference purposes, the relevant literature data are reported in the Supporting Information.…”

Carbon Assimilation

“…To explain this he puts forward exactly the same hypothesis that ' It is interesting to note that the solubility of carbon dioxide in some alcohols and esters is much greater than in water, see ¢.g., Just (1901). The present state of the subject is the result of a number of independent investigations, the bearing of which on one another is rather accidental than designed, and in this lack of co-ordination is to be found a reason for the slow development of the subject hitherto.…”

Carbon Assimilation

“…This last sentence suggests that Willstatter is unaware of Siegfried's work. ' It is interesting to note that the solubility of carbon dioxide in some alcohols and esters is much greater than in water, see e.g., Just (1901). CHAPTER VI11.…”