Starch contributes 70 – 80% of calories in diets and is a key source of glucose and energy for humans; and also finds non‐food applications due to its abundance, renewability, and biodegradability. The conventional starch sources of cassava, potato, wheat, and maize have been widely studied and overexploited; thus, there is increasing interest in the utilization and applications of a great variety of underutilized, non‐conventional, and novel starch sources with singular characteristics, but their technological applications are still at infancy. Non‐conventional starches display comparable properties to conventional starches, and their exploitation is linked to regional availability, the social and cultural significance of the starch sources, by‐product valorization, and technological advantages over conventional starches. They can compete favorably with or complement conventional starches for domestic and industrial applications, but information on these starches is still limited to fundamental knowledge. The unification and standardization of research methods are vital for improving yield, purity, and appropriate data comparison. In‐depth studies are also necessary for a proper understanding of the structure‐function‐utilization relationships of the individual sources, in addition to modification strategies for expanding their range of functionalities and providing the framework for novel and extended applications. This review aims to present a comparative state of the art on the sources, characteristic compositions, properties, and techno‐functional applications of non‐conventional starches. Suggestions on future research interests are also proposed to further improve the understanding and expand the potential utilizations of non‐conventional starches
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