Low- and high-frequency conductivities of RbAg4I5 and Ag β″-alumina at low temperatures

Kurzeja, D.; Nold, Michael; Ebert, M.; Staikov, G.; Lorenz, W.J.; Froese, A.; Speck, R.; Wiesbeck, W.; Bréiter, M.W.

doi:10.1016/0167-2738(93)90034-z

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Cited by 9 publications

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“…By analogy with traditional ceramic electrolytes, such as NaβAl 2 O 3 24, 25 and RbAg 4 I 5, 26, 27 the structures of the β‐CD–PEO/Li + and β‐CD–PEO/Na + complex crystals are quite intriguing. The assembled structure of PEO and β‐CD forms the frame structure, where the aligned β‐CDs form the nanochannels providing directional vacancies/interstitials for the transport of the alkali metal ions.…”

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confidence: 99%

Ionic Conductivity of β‐Cyclodextrin–Polyethylene‐Oxide/Alkali‐Metal‐Salt Complex

Yang

Chen

et al. 2015

Chemistry A European J

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Highly conductive, crystalline, polymer electrolytes, β-cyclodextrin (β-CD)-polyethylene oxide (PEO)/LiAsF6 and β-CD-PEO/NaAsF6 , were prepared through supramolecular self-assembly of PEO, β-CD, and LiAsF6 /NaAsF6 . The assembled β-CDs form nanochannels in which the PEO/X(+) (X=Li, Na) complexes are confined. The nanochannels provide a pathway for directional motion of the alkali metal ions and, at the same time, separate the cations and the anions by size exclusion.

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confidence: 99%