Low-carbon footprint diluents in solvent extraction for lithium-ion battery recycling

Ahamed, Aboudaye M.; Swoboda, Benjamin; Arora, Zubin; Lansot, Jean Yves; Chagnes, Alexandre

doi:10.1039/d3ra04679f

RSC Adv.

2023

DOI: 10.1039/d3ra04679f

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Low-carbon footprint diluents in solvent extraction for lithium-ion battery recycling

Aboudaye M. Ahamed,

Benjamin Swoboda,

Zubin Arora

et al.

Abstract: This study investigated the influence of low-carbon footprint diluents and diluents from petroleum industry on Co(ii), Ni(ii), Mn(ii), Li(i) and Cu(ii) extraction by Cyanex® 272, DEHPA and Acorga® M5640.

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Cited by 3 publications

References 57 publications

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This review highlights the use of CO2 as a reagent in hydrometallurgy, with emphasis on the new concept of circular hydrometallurgy. It is shown how waste CO2 can be utilised in hydrometallurgical operations for pH control or regeneration of acids for leaching. Metal‐rich raffinate solutions generated after removal of the valuable metals can serve as feedstocks for mineral carbonation, providing alternative avenues for CO2 sequestration. Furthermore, CO2 can also be used as a renewable feedstock for the production of chemical reagents that can find applications in hydrometallurgy as lixiviant, as precipitation reagent or for pH control. Mineral carbonation can be combined with chemical reactions involving metal complexation reagents, as well as with solvent extraction processes for the concurrent precipitation of metal carbonates and acid regeneration. An outlook for future research in the area is also presented.

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Carbon Dioxide as a Sustainable Reagent in Circular Hydrometallurgy

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ChemSusChem

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show abstract

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Low-carbon footprint diluents in solvent extraction for lithium-ion battery recycling

Abstract: This study investigated the influence of low-carbon footprint diluents and diluents from petroleum industry on Co(ii), Ni(ii), Mn(ii), Li(i) and Cu(ii) extraction by Cyanex® 272, DEHPA and Acorga® M5640.

Cited by 3 publications

References 57 publications

Carbon Dioxide as a Sustainable Reagent in Circular Hydrometallurgy

Carbon Dioxide as a Sustainable Reagent in Circular Hydrometallurgy

Analysis of extractant loss in the process of separation nickel and magnesium from spent LIBs by HCA

A new solvent extraction technology and mechanism for the separation and recovery of Li+ using benzene sulfonamide acid substance

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