This article presents the analysis of the electromagnetic (EM) properties of a novel metamaterial (MM) array in the microwave frequency range. The background for this work is the rapid development of portable devices with low individual energy consumption for the so-called “Internet of Things” (IoT) and the demand for energy harvesting from the environment on a micro scale through harvesters capable of powering billions of small receivers globally. The main goal of this work was to check the potential of the novel MM array structure for EM energy harvesting. The proposed MM array was analyzed in the CST Studio simulation environment. This resulted in the determination of the substitute average EM parameters (absorption, reflection, and transmission) of the MM array. Then, the MM array was manufactured, and the simulation results of the MM array parameters were experimentally validated in a microwave waveguide test system. Based on this conclusion, a prototype of the microwave MM absorber, together with an RF/DC converter, was designed and manufactured for harvesting EM energy from the environment. The system’s energy efficiency was evaluated, and its potential application in energy harvesting technology was appraised. Using a microwave horn antenna, the EM energy harvesting efficiency of the prototype was evaluated. It was about 50% at a microwave frequency of about 2.6 GHz. This may make the prototype attractive as an EM energy harvester or bolometric sensor.