“…Detection system Spectrophotometric [5] Spectrophotometric [6] Chemiluminescence [7] Spectrophotometric [8] Spectrophoto -metric [9] [60,62,64] *Rapid measurement [60,66,67] *Low-cost system [60,67] *High throughput [60,62,66,64] *Easy to assemble [60] *Easy to operate [61] *Optimum sensitivity [66] *Good sensitivity [61,66,67] *Good repeatability [66] *Low reagent consumption [60,62,66] *Minimum waste generation [66] *Minimum man power/labour to run the experiment [60,62] *Exposure to hazardous reagents such as cadmium [60,62] *Interference of other contaminants such as phosphate, Co (11) and Fe(111) [60,62,66] *Tedious procedure for reagent preparation Near-to-surface properties such as conductivity, dielectric and permeability of an analyte solution can be determined via PESA. It is reported that PESA has the ability to detect and estimate nitrate in water samples [3,6,7,19,48,49,…”