Abstract:Cimitrypazepines
are a class of natural products produced
by Pictet–Spengler
condensation of N
ω-methylserotonin
and aldehydes in a manner that produces a seven-membered azepine ring.
In this study, the fragmentation behavior of this class of molecules
under low-energy CID was investigated in detail. Proposed mechanisms
of fragmentation were supported by deuterium labeling and DFT calculations.
Loss of methylamine and methylenimine were dominant fragmentation
pathways of analogs containing an aliphatic side ch… Show more
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