2023
DOI: 10.1021/jasms.2c00247
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Low Energy Collision-Induced Dissociation of Azepine Pictet–Spengler Adducts of Nω-Methylserotonin

Abstract: Cimitrypazepines are a class of natural products produced by Pictet–Spengler condensation of N ω-methylserotonin and aldehydes in a manner that produces a seven-membered azepine ring. In this study, the fragmentation behavior of this class of molecules under low-energy CID was investigated in detail. Proposed mechanisms of fragmentation were supported by deuterium labeling and DFT calculations. Loss of methylamine and methylenimine were dominant fragmentation pathways of analogs containing an aliphatic side ch… Show more

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