A novel pathway for the formation of multi-particle-multi-hole (np − mh) excited states in rare isotopes is reported from highly energy-and momentum-dissipative inelastic-scattering events measured in reactions of an intermediate-energy beam of 38 Ca on a Be target. The negative-parity, complex-structure final states in 38 Ca were observed following the in-beam γ-ray spectroscopy of events in the 9 Be( 38 Ca, 38 Ca + γ)X reaction in which the scattered projectile lost longitudinal momentum of order ∆p || = 700 MeV/c. The characteristics of the observed final states are discussed and found to be consistent with the formation of excited states involving the rearrangement of multiple nucleons in a single, highly-energetic projectile-target collision. Unlike the far-less dissipative, surface-grazing reactions usually exploited for the in-beam γ-ray spectroscopy of rare isotopes, these more energetic collisions appear to offer a practical pathway to nuclear-structure studies of more complex multi-particle configurations in rare isotopes -final states conventionally thought to be out of reach with high-luminosity fast-beam-induced reactions.