The negative-parity states of 24Mg nucleus are investigated within the shell model. We are based on the calculations of energy levels, total squared form factors, and transition probability using the p-sd-pf (PSDPF) Hamiltonian in a large model space (0 + 1) hW. The comparison between the experimental and theoretical states showed a good agreement within a truncated model space. The PSDPF-based calculations successfully reproduced the data on the total squared form factors and transition probabilities of the negative-parity states in 24Mg nucleus. These quantities depend on the one-body density matrix elements that are obtained from the PSDPF Hamiltonian. The wave functions of radial one-particle matrix elements calculated with the harmonic-oscillator potential are suitable to predict experimental data by changing the center-of-mass corrections.