Hybrid rocket combustion displays low frequency instability(LFI, 10~30Hz) at a certain condition. Vortex shedding in the post-chamber is suspected to cause the occurrence of Also POD analysis shows that dominant symmetric spatial modes in the stable combustion shift suddenly into asymmetric spatial pattern with the appearance of LFI. Especially, the appearance of mode 3 is a typical change of flow dynamics in unstable combustion representing a rotational fluid motions associated with vortex shedding.