Low Friction-Coefficient TiBCN Nanocomposite Coatings Prepared by Cathode Arc Plasma Deposition

Abstract

TiBCN nanocomposite coatings were deposited on cemented carbide and Si (100) by a cathode arc plasma system, in which TiB2 cathodes were used in mixture gases of N2 and C2H2. X-ray diffraction shows that TiB2 and Ti2B5 peaks enhance at low flow rates of C2H2, but they shrink when the flow rate is over 200 sccm. An increase of deposition rate was obtained from different TiBCN thicknesses for the same deposition time measured by scanning electron microscopy. Atomic force microscopy shows that the surface roughnesses are ∼10 nm and ∼20 nm at C2H2 flow rates of 0-100 sccm and of 150-300 sccm, respectively. High resolution transmission electron microscopy and X-ray photoelectron spectroscopy show that the coatings consist of nanocrystal phases Ti2B5, TiB2 and TiN, and amorphous phase carbon and BN. The average crystal sizes embedded in the amorphous matrices are 200 nm and 10 nm at C2H2 flow rates of 200 sccm and 300 sccm, respectively. In Raman spectra, the D-and G-bands increase with C2H2 flows at low flow rates, but weaken at high flow rates. The microhardness of the coatings decreases from 28.6 GPa to 20 GPa as the C2H2 increases from 0 sccm to 300 sccm, and the ball-on-disk measurement shows a dramatic decrease of the friction coefficient from 0.84 to 0.13. The reason for the reduced hardness and friction coefficient with the change of C2H2 flow rates is discussed.

Investigation of structure and mechanical properties of plasma vapor deposited nanocomposite TiBN films

“…The effect of nitrogen flow on TiBN coating deposited on cold work tool steel and silicon wafers by closed field unbalanced magnetron sputtering was studied elsewhere (Cicek et al) [18]. The nitrogen partial pressure study on nitride films of transition metal provided direction for our present work [19]. There is a lot of work on the hardness of TiBN coating [20][21][22], but little work was done on the effect of varying the partial pressures of N 2 under a constant total pressure.…”