Low-melting frits are most often applied in the form of coatings for ceramic building materials, i.e., roof tiles and brick façade. A thin layer of glaze or sintered engobe improves decorative and functional properties of the final product. The roof tiles are fired in the low temperature range (1000-1200°C). There are expected solutions which will allow obtaining a smooth layer of glaze without deteriorating mechanical and chemical properties. Thus, it is important to find a solution that meets the above requirements. The aim of this study was to analyze the effect of bismuth (III) oxide on the properties of low-melting different commercial frits used as a main component of glaze for ceramic roof tiles. Three commercial frits were modified with the addition of bismuth (III) oxide in the amount of 5 and 10 wt%. In the first stage, the results of the dilatometric and high-temperature microscopy analysis are shown. Keywords Low-melting frits. Ceramic roof tiles. Low-melting glaze. Bismuth (III) oxide Bi 2 O 3