We measured the three-dimensional velocity field of a large-scale reorientation in turbulent Rayleigh-Bénard convection with a high Rayleigh number Ra = $2.5\cdot 10^9$ by long-term particle tracking velocimetry measurements over 30 hours in a water-filled cubic cell with a side length of $L=300$ mm. Reorientations are characterized by the large-scale circulation in the flow changing its orientation from one cell diagonal to the other, and they are rare events; one can expect about one reorientation per day in our measurement. No other three-dimensional velocity field measurements of such events are known in the literature. Dominant flow structures during the reorientation are extracted from the measurement data using POD. The convergence of the POD is supported by applying the symmetries of the cubic RB cell to our data set to make it equiprobalbe so that it mimics a long time series of reorientation events. The decomposition reveals degenerate mode pairs, i.e. modes that have the same energy and describe the same state, which is consistent with reorientation results found in the literature for DNS of turbulent RBC in cubic cells. The first six modes of the decomposition account for about 70\% of the total energy and contain the most important coherent structures in the system. Modes 1-3 reflect the orientation and dynamics of the large-scale circulation, i.e., the primary flow structure, and modes 4-6 provide the orientation and dynamics of corner circulations, i.e., the secondary flow structures. A pure $Y$ roll structure is observed in the middle of the reorientation event.