“…This is because that the plasma process makes the PULK film surface become densification and introduce the silanol specie into the PULK film, which increases the dielectric constant value of the PULK film. Recently, some references have reported that the PULK film damages are caused by the dry etching/ashing [14,15], wet cleaning [16], PVD (Physical Vapor Deposition) [17] and CMP (Chemical mechanical polisher) [18,19]. The above mentioned damages not only cause the carbon loss of the PULK film but also make the PULK film performance convert from hydrophobe to hydrophilization.…”