Low-temperature and low-pressure effective fluorescence lifetimes and spectra of gaseous anisole and toluene

Abstract

Fluorescence spectra and lifetimes of anisole and toluene vapor in nitrogen have been measured at conditions below ambient (257–293 K and 100–2000 mbar) upon excitation with 266-nm laser light to expand the applicable range of anisole and toluene laser-induced fluorescence (LIF) for conditions below room temperature that occur in expanding flows and cases with strong evaporative cooling. Anisole fluorescence spectra broaden with decreasing pressure while fluorescence lifetimes decrease simultaneously. This is consistent with a more pronounced effect of internal vibrational redistribution on the overall fluorescence signal and can be explained by significantly reduced collision rates. In the case of toluene, the transition from photo-induced heating to photo-induced cooling was observed for the first time for 266 nm. The data confirm predictions of earlier work and is particularly important for the advancement of the available photo-physical (step-ladder) models: since those transitions mark points where the molecules are already thermalized after excitation (i.e., no vibrational relaxation occurs during deactivation), they are important support points for fitting empirical parameters and allow analytical determination of the ground state energy transferred to the excited state. The data enable temperature and/or pressure sensing, e.g., in accelerating cold flows using laser-induced fluorescence of both tracers.

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“…Each of them has its own particular width and relative height. Beuting et al 11 present studies about the fluorescence of toluene vapor at wavelengths below 330 nm, also excited by a 266 nm laser, and reports a peak from approximately 265 and 330 nm and centered about 280 nm, which is in partial accordance with the value 309 nm.…”

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“…However, increased collisions from the longer conjugation in Fs-Pt-2 lead to a decrease in E(v″) and consequently a blue shift. 34,35 After polymerization (Figure 3e,f), the presence of rigid polymer chains improves the harmonic behavior between S 0 and S 1 and inhibits chromophore collisions. As a result, the spectral shift remains relatively stable with temperature variations.…”