Low Temperature Catalytic Decomposition of Hydrogen Sulfide into Hydrogen and Diatomic Gaseous Sulfur

Startsev, A. N.; Kruglyakova, O. V.; Chesalov, Yu. A.; Ruzankin, Sergey Ph.; Kravtsov, Evgenii A.; Larina, T. V.; Паукштис, E. A.

doi:10.1007/s11244-013-0061-y

Cited by 48 publications

(30 citation statements)

References 44 publications

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“…Today the strict nuclear physics does not assume nuclear reactions at small energies and that contradict experimental data [54,55]. Here we should also note our skepticism towards the idea of nuclear fusion in Tokomaks, we consider this way as hopeless.…”

Section: The Standard Modelmentioning

confidence: 92%

“…But the use of the reactions of classical cold fusion for the power output is also difficult due to the complexity of colliding nuclei phasing [32,33]. This phenomenon is well described by the equation with oscillating charge, while the cold nuclear fusion had been predicted in UQT 6 years before its real discovery [7,11,[15][16][17][18][19][20][54][55][56]. It was discovered long ago that nuclear transmutations are widely spread (it is especially evident for plants and biological objects), but they are faintly connected with energy liberation.…”

Section: The Standard Modelmentioning

confidence: 99%

“…Apparently, that is absolutely new type of nuclear transmutations unacknowledged by modern nuclear science, but experimentally discovered sufficiently long ago. Today there are a lot of experimental data confirming the mass character of nuclear transmutation [32,33,[54][55][56]. Moreover there are many projects of nuclear waste neutralization that use this method.…”

Section: The Standard Modelmentioning

confidence: 99%

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Short Review of the Unitary Quantum Theory

Sapogin¹,

Dzhanibekov²,

Ryabov³

2017

THE IJES

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Section: The Standard Modelmentioning

confidence: 92%

Section: The Standard Modelmentioning

confidence: 99%

Section: The Standard Modelmentioning

confidence: 99%

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Short Review of the Unitary Quantum Theory

Sapogin¹,

Dzhanibekov²,

Ryabov³

2017

THE IJES

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“…Experimental techniques for decomposing hydro gen sulfide in the flow gas phase, autoclave, and triple phase regimes were described in [3][4][5]. Our Raman scattering spectra were recorded on a RFS 100/S Bruker FT Raman spectrometer (Germany) in the range of 100-3600 cm -1 .…”

Section: Methodsmentioning

confidence: 99%

“…Never theless, there are colloid hydrophobic sols of S 8 sulfur, 0.1-1.0 µm in size, that are thermodynamically unstable with respect to their transformation into orthorhombic sulfur S 8 [2]. At the same time, the diatomic gaseous sulfur formed during the decompo sition of hydrogen sulfide on metallic catalysts at room temperature is readily soluble in water until its con centration exceeds 0.5 wt % [3][4][5]:…”

Section: Introductionmentioning

confidence: 99%

Aqueous solutions of sulfur produced via low-temperature hydrogen sulfide catalytic decomposition

Startsev

Kruglyakova

Chesalov

et al. 2014

Russ. J. Phys. Chem.

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White globules of solid sulfur modification are obtained from saturated aqueous solutions. The chemical composition, morphology, and structure of the white sediment are investigated by means of X ray fluorescence analysis, scanning electron microscopy, and high resolution transmission electron microscopy. It is shown that the white sediment contains an unknown modification of globular hexagonal sulfur with glob ule sizes of 5-10 μm and interplanar distances of 0.45, 0.29, and 0.15 nm. A single absorption band at 880 cm -1 is found in the Raman scattering spectra of the saturated solutions above the sediment. It is sug gested that the white sediment consists of condensed S 2 phase.

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Sulfoxylic and Thiosulfurous Acids and their Dialkoxy Derivatives

Макаров¹,

Makarova

Silaghi‐Dumitrescu

2014

Patai's Chemistry of Functional Groups

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Being potent reductants, sulfoxylic acid S(OH) 2 and its salts (sulfoxylates) are intermediates in many reactions of important industrial chemicals, such as sodium hydroxymethanesulfinate (rongalite) and thiourea dioxide. Sulfoxylates contain the ‐O‐S‐O‐ moiety, which is isoelectronic to trioxides, ‐O‐O‐O‐. However, the apparent structural and valence electron count similarity may be contrasted to significant differences in reactivity. Thiosulfurous acid H 2 S 2 O 2 is a primary product of reaction between hydrogen sulfide and sulfur dioxide. Despite the central role of the S‐S bond in organic, inorganic and biological chemistry, thiosulfurous acid remains one of the least studied sulfur acids together with its one sulfur counterpart–sulfoxylic acid. Here we present the first special review describing the structure, stability and reactivity of these acids and their anions. Organic derivatives of sulfoxylic and thiosulfurous acids are much more studied than the acids themselves. In this review, organic derivatives of sulfoxylic and thiosulfurous acids (dialkoxy sulfoxylates (R‐O‐S‐O‐R) and dialkoxy disulfides (R‐O‐S‐S‐O‐R), which are isoelectronic to organic trioxides and tetroxides), as well as organic trisulfanes R‐S‐S‐S‐R and tetrasulfanes R‐S‐S‐S‐S‐R, respectively, are also briefly discussed.

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Low Temperature Catalytic Decomposition of Hydrogen Sulfide into Hydrogen and Diatomic Gaseous Sulfur

Cited by 48 publications

References 44 publications

Short Review of the Unitary Quantum Theory

Short Review of the Unitary Quantum Theory

Aqueous solutions of sulfur produced via low-temperature hydrogen sulfide catalytic decomposition

Sulfoxylic and Thiosulfurous Acids and their Dialkoxy Derivatives

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