2010
DOI: 10.1002/zaac.201000066
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Low Temperature Flux Synthesis and Characterizations of a New Layered Barium Borate BaB8O11(OH)4 

Abstract: The new hydroxyl barium borate BaB8O11(OH)4 was synthesized by using a low‐temperature molten salt technique with boric acid as flux at 458 K. Its crystal structure was determined from single‐crystal X‐ray data. The compound crystallizes in the monoclinic space group P121/n1 (No.14) with unit cell of a = 790.80(16) pm, b = 1393.9(3) pm, c = 1004.7(2) pm, β = 90.00(3)°, V = 1107.6(4) × 106 pm3, Z = 2. It is isostructural to PbB8O11(OH)4, but obviously different from AB8O11(OH)4 (A = Ca, Sr) in cell. The crystal… Show more

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Cited by 13 publications
(1 citation statement)
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“…The bands visible at 1454 and 1464 cm –1 in the spectra of the Nd 3+ and Sm 3+ compounds, respectively, can be attributed to ν 4 NO 3 vibrations . The pronounced bands at 1614 and 1612 cm –1 from the Nd 3+ and Sm 3+ compounds, respectively, are likely to stem from H–O–H bending; OH group stretching vibrations causing intense broad absorptions at around 3200 cm –1 are visible in both IR spectra …”
Section: Resultsmentioning
confidence: 90%
“…The bands visible at 1454 and 1464 cm –1 in the spectra of the Nd 3+ and Sm 3+ compounds, respectively, can be attributed to ν 4 NO 3 vibrations . The pronounced bands at 1614 and 1612 cm –1 from the Nd 3+ and Sm 3+ compounds, respectively, are likely to stem from H–O–H bending; OH group stretching vibrations causing intense broad absorptions at around 3200 cm –1 are visible in both IR spectra …”
Section: Resultsmentioning
confidence: 90%