Low Temperature Pyrolysis of Boron Trifluoride—Mannich Base Complexes. 2-Nitro-1-alkenes<sup>1</sup>

Emmons, William D.; Cannon, William N.; Dawson, J. W.; Ross, Robert M.

doi:10.1021/ja01104a508

Cited by 12 publications

(2 citation statements)

References 2 publications

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“…These transformations require slightly lower temperatures and give expected products with satisfactory yields. The example is the preparation of 2-nitrobut-1-ene [68] (Fig. 19.).…”

Section: Deaminationmentioning

confidence: 99%

Preparation of conjugated nitroalkenes: short review

Zawadzińska¹,

Gaurav²,

Jasiński³

2022

Sci. Rad

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“…These transformations require slightly lower temperatures and give expected products with satisfactory yields. The example is the preparation of 2-nitrobut-1-ene [68] (Fig. 19.).…”

Section: Deaminationmentioning

confidence: 99%

Preparation of conjugated nitroalkenes: short review

Zawadzińska¹,

Gaurav²,

Jasiński³

2022

Sci. Rad

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“…The dispersion (nFnc) was found to vary nearly linearly with Mn2aO, and with n, the number of carbons, giving, by least squares fit, nF -nc = 0.0208-3.2 x 10 Abrí) (9) and nF-nc = 0.0188 -6.5 x l(T4n Eq. 5 Obsd.…”

Section: T H I S C O N T E N T Imentioning

confidence: 97%

Physical Property Correlations for Conjugated Aliphatic Nitroolefins. Refractive Index, Density, and Boiling Point.

Lampe¹,

Mende²,

Mills³

1962

J. Chem. Eng. Data

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The EFFECT of the conjugated nitro-olefin group on various physical properties has been determined. The boiling points at 10 mm. and the refractive indices and densities at 30°, 40°, and 60°C. were measured for a series of 21 conjugated linear nitro-olefins having straight-chain 22 Nitroethylene 35 4-Methyl-3-nitro-2-pentene 23 1-Nitropropene 36 2,3-Dimethyl-l-nitro-1-butene 24 2-Nitropropene 37 1-Nitro-l-heptene 25 1-Nitro-l-butene 38 2-Nitro-l-heptene 26 2-Nitro-l-butene 39 5-Methyl-3-nitro-3-hexene 27 2-Methyl-l-nitro-l-propene 40 1-Nitro-l-octene 28 1-Nitro-l-pentene 41 2-Methyl-3-nitro-3-heptene 29 2-N itro-1 -pentene 42 4-Ethyl-2-nitro-2-hexene 30 3-Methyl-l-nitTO-l-butene 43 5-Ethyl-3-nitro-3-heptene 31 1-Nitro-l-hexene 44 3-Nitro-3-decane 32 2-Nitro-l-hexene 45 4-Ethyl-3-nitro-2-Octene 33 34

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Nitroparaffins

Bollmeier¹

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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Four nitroparaffins are commercially available. These four, nitromethane, nitroethane, 1‐nitropropane, and 2‐nitropropane, are medium‐boiling liquids which are excellent solvents for a wide variety organic compounds and polymers. Some physical properties of these nitroparaffins and a few higher mononitroparaffins and polynitro compounds are presented. The nitroparaffins can undergo a number of reactions which give them utility for synthesis of other compounds of commercial importance. These reactions are discussed. Of particular importance is their ability to form nitronate salts with alkalis. This reaction is the first step for the halogenation reaction, eg, for the synthesis of the fumigant chloropicrin, or the condensation with carbonyl compounds for the synthesis of nitro alcohols. Production of the four commercial nitroparaffins is by vapor‐phase nitration of propane with nitric acid. Some 41,000 t of mixed nitroparaffins can be produced annually. All the nitroparaffins are flammable liquids. Their principal hazard is by inhalation. Special attention is required for handling nitromethane because it can be detonated under certain circumstances. The bulk of nitroparaffin production is used for synthesis of other chemical products. Nitromethane is useful as a fuel in drag racing and model airplanes, however, and nitroethane and 1‐nitropropane see use as solvent in coatings.

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Low Temperature Pyrolysis of Boron Trifluoride—Mannich Base Complexes. 2-Nitro-1-alkenes¹

Cited by 12 publications

References 2 publications

Preparation of conjugated nitroalkenes: short review

Preparation of conjugated nitroalkenes: short review

Physical Property Correlations for Conjugated Aliphatic Nitroolefins. Refractive Index, Density, and Boiling Point.

Nitroparaffins

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Low Temperature Pyrolysis of Boron Trifluoride—Mannich Base Complexes. 2-Nitro-1-alkenes1

Cited by 12 publications

References 2 publications

Preparation of conjugated nitroalkenes: short review

Preparation of conjugated nitroalkenes: short review

Physical Property Correlations for Conjugated Aliphatic Nitroolefins. Refractive Index, Density, and Boiling Point.

Nitroparaffins

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Product

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Low Temperature Pyrolysis of Boron Trifluoride—Mannich Base Complexes. 2-Nitro-1-alkenes¹