Abstract:A series of 9%CeO x -MnO x /TiO 2 -GO nanocomposites with different molar ratios of Ce/Mn were synthesized by the sol-gel and ultrasonic impregnation methods and characterized by field emission scanning electron microscope (FESEM), high resolution transmission electron microscopy (HRTEM), N 2 adsorption (BET) analysis, X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR). The results showed that various valences of Ce and Mn oxides were uniformly distributed on the surface of TiO 2 -GO multilayered supports. The coexistence of various valences of Ce and Mn oxides can improve the redox performance of the catalyst. With the introduction of Ce, the amount of MnO 2 and non-stoichiometric MnO x /Mn, the total oxygen and chemisorbed oxygen content, and the electron transfer ability of the catalyst increased significantly. When the molar ratio of Ce/Mn was 0.3, the catalysts exhibited high selective catalytic reduction activity (more than 99% at 180 • C) and N 2 selectivity. The presence of hydrophilic groups on the surface of the GO was considered as the critical factor influencing the H 2 O resistance of the catalyst. Due to the pre-sulfuring process of GO, serious sulfation of the active component can be prevented, and the catalyst exhibited excellent SO 2 resistance.