Low temperature sintering and dielectric properties of BaTiO3 with glass addition

Effect of fluxing additive on sintering temperature, microstructure and properties of BaTiO3

“…• C without the formation of a second phase, but with a dielectric constant of only 994 (Hsiang et al 2009).…”

Characteristics of BaO–B2O3–SiO2 nano glass powders prepared by flame spray pyrolysis as the sintering agent of BaTiO3 ceramics

“…However, in order to achieve BaTiO 3 with a high density and high dielectric constant, high sintering temperatures above 1300 • C is required. At present, adding glass with a low melting point is an effective and inexpensive way to reduce the sintering temperature of BaTiO 3 -based ceramics [3][4][5][6][7][8][9]. Jeon et al showed the effects of BaO-B 2 O 3 -SiO 2 glass additive on densification and dielectric properties of BaTiO 3 ceramics started from hydrothermally synthesized nano-sized BaTiO 3 powders (∼60 nm) [5].…”

“…Addition of an optimal amount of the BaO-B 2 O 3 -SiO 2 glass to BaTiO 3 compacts accelerated densification with a limited grain growth. Hsiang et al investigated the effects of various glasses (BaO-B 2 O 3 -SiO 2 , PbO-B 2 O 3 -SiO 2 , and ZnO-B 2 O 3 -SiO 2 ) addition on both the sintering behavior and dielectric properties of BaTiO 3 [6]. The results indicated that ZnO-B 2 O 3 -SiO 2 glass could be used as a sintering aid to reduce the sintering temperature of BaTiO 3 from 1300 • C to 900 • C without the formation of secondary phase.…”

“…After milling process followed the post-treatment process, nano-sized BaTiO 3 powders with non-aggregation characteristics could be obtained [15,16]. However, micron or submicron size glass powders with irregular morphology prepared by conventional melting process have been mainly used to decrease the sintering temperature of BaTiO 3 ceramic [3][4][5][6][7][8][9]. Nanosized glass powders have not been applied as the sintering agent for BaTiO 3 ceramics.…”

Structure and dielectric behavior of nano-structure ferroelectric BaxSr1−xTiO3 prepared by sol–gel method

“…. [1][2][3][4][5][6][7][8][9][10][11][12]. The most remarkable property of BT and BST is related to its high dielectric constant, where the room temperature dielectric constant of BaTiO 3 ceramics is known to be greater than 2000 [13].…”