Low temperature steam reforming of methane over Ni–Ce(1−)Zr()O2 catalysts under severe conditions

Roh, Hyun Seog; Eum, Ic Hwan; Jeong, Dae-Woon

doi:10.1016/j.renene.2011.08.013

Cited by 126 publications

(60 citation statements)

References 25 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Reducible supports such as CeO 2 and CeO 2 -ZrO 2 mixed oxides are also good candidates for low temperature MSR due to the active role in the redox mechanism through the mobility of surface oxygen species [16][17][18][19][20][21][22][23]. The oxygen storage capacity of CeO 2 -ZrO 2 can be improved by the addition of La [24] thus, enhancing the resistance toward carbon formation [25,26] and the thermal stability of the catalyst [27].…”

Section: Introductionmentioning

confidence: 99%

Catalyst development for steam reforming of methane and model biogas at low temperature

Angeli

Turchetti

Monteleone

et al. 2016

Applied Catalysis B: Environmental

137

View full text Add to dashboard Cite

Section: Introductionmentioning

confidence: 99%

Catalyst development for steam reforming of methane and model biogas at low temperature

Angeli

Turchetti

Monteleone

et al. 2016

Applied Catalysis B: Environmental

137

View full text Add to dashboard Cite

“…In particular, CeO 2 -supported Ni catalysts have been studied widely and reported to be significantly active and selective for hydrogen production from SR reactions [19,23]. These studies concluded that a good oxygen-storage capacity is beneficial for eliminating coke species on the catalyst surface [23].…”

Section: Introductionmentioning

confidence: 99%

Dynamic hydrogen production from ethanol steam-reforming reaction on Ni_xMo_y/SBA-15 catalytic system

Kim

Kwak

Park

et al. 2014

Int. J. Energy Res.

View full text Add to dashboard Cite

SUMMARYThis study examined the effects of advanced bimetallic catalytic species of Ni and Mo on hydrogen production from ethanol steam reforming. Ni x Mo y /SBA-15 exhibited significantly higher ethanol steam-reforming activity at mild temperatures than monometallic Ni/SBA-15; the highest activity was achieved using the Ni 0.95 Mo 0.05 /SBA-15 catalyst. H 2 production and ethanol conversion were maximized at 70-87% and 90-92%, respectively, over the temperature range of 500 to 800°C with an EtOH : H 2 O ratio of 1:3 and a gas hourly space velocity of 3000 h À1 . This highlights the synergy between the Ni and Mo loading on SBA-15 during ethanol steam reforming through the inhibition of Ni particle agglomeration and the consequent decrease in catalytic deactivation. In the proposed mechanism for ethanol steam reforming, Mo oxide promotes CH 4 -steam reforming at lower temperatures and depresses the CO-water gas shift reaction. Overall, hydrogen production is significantly higher over Ni x Mo y /SBA-15 than over monometallic Ni/SBA-15 despite the evolution of CO gas.

show abstract

“…Preparation Ni-CeO 2 /γ-Al 2 O 3 : Raw gas from gasification was reformed using Ni-CeO 2 /γ-Al 2 O 3 catalyst which was made modified from the reports [6,8,11,12]. Preparation of Ni-CeO2/γ-Al 2 O 3 catalysts involved two steps: CeO 2 was first coated onto porous γ-Al 2 The other form of the catalysts, called "carboneous catalysts" was synthesized.…”

Section: Experimental Sample Preparationmentioning

confidence: 99%

“…Tar can be decomposed at temperatures >800°C and can partially eliminated by the addition of different catalysts [6]. The produced gas, called syngas in this study, is a mixture of carbon monoxide (CO), hydrogen (H2), methane (CH4), and other hydrocarbon gases (CxHyOz), of which the gaseous fuels are not acceptable for the usage of the fuel for solid oxide fuel cells (SOFCs).…”

Section: Introductionmentioning

confidence: 99%

Gasification and Syngas Reforming of City Waste Papers for Solid Oxide Fuel Cells

Sy¹,

Yy²,

Wcj³

2017

Innov Ener Res

View full text Add to dashboard Cite

This study has investigated the thermal processes of three types of Municipal Solid Wastes (MSW) in Taipei. Three key properties of the processes are concerned, the formation of tar, the sulfur content, and the reforming of CH 4 as the syngas is used for Solid Oxide Fuel Cells (SOFCs). K 2 CO 3 is used as a catalyst to reduce the amount of tar. One of tar production from MSW is reduced from 37.2 wt% to 13.7 wt%. The raw syngas from gasification is then reformed using a Ni-CeO 2 catalyst on a γ-Al 2 O 3 support to optimize the quantity of H 2 and reduce the CH 4 content. H 2 S generated by waste paper is in a level of 1.83 ppm, and reduced to 0.04 ppm by CaCO 3 . Syngas with a composition of 51.3 vol% H 2 , 44.8 vol% CO and 3.4 vol% CH 4 is used for the power generation by a selfassembled SOFC. The best power density is 269 mW.cm -2 at 800°C, which is inferior to the maximum value of 326 mW.cm -2 for a cell that uses H 2 as the fuel.

show abstract

Low temperature steam reforming of methane over Ni–Ce(1−)Zr()O2 catalysts under severe conditions

Cited by 126 publications

References 25 publications

Catalyst development for steam reforming of methane and model biogas at low temperature

Catalyst development for steam reforming of methane and model biogas at low temperature

Dynamic hydrogen production from ethanol steam-reforming reaction on Ni_xMo_y/SBA-15 catalytic system

Gasification and Syngas Reforming of City Waste Papers for Solid Oxide Fuel Cells

Contact Info

Product

Resources

About

Low temperature steam reforming of methane over Ni–Ce(1−)Zr()O2 catalysts under severe conditions

Cited by 126 publications

References 25 publications

Catalyst development for steam reforming of methane and model biogas at low temperature

Catalyst development for steam reforming of methane and model biogas at low temperature

Dynamic hydrogen production from ethanol steam-reforming reaction on NixMoy/SBA-15 catalytic system

Gasification and Syngas Reforming of City Waste Papers for Solid Oxide Fuel Cells

Contact Info

Product

Resources

About

Dynamic hydrogen production from ethanol steam-reforming reaction on Ni_xMo_y/SBA-15 catalytic system