2020
DOI: 10.1007/s10854-020-04580-4
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Low-temperature synthesis of Ti3Al(Sn)C2 solid solution using replacement reaction

Abstract: The synthesis of Ti 3 Al(Sn)C 2 usually uses elemental powder as the raw material, and the synthesis temperature is up to 1500°C. Low-temperature ceramic sintering is the key to inhibit the formation of competitive phases and reduce the ceramic sintering cost. In this paper, a new method of low-temperature synthesis of Ti 3 Al(Sn)C 2 was proposed, and high-purity Ti 3 Al(Sn)C 2 sample was successfully prepared at low temperature by using the replacement reaction method. Research shows that the temperature of 6… Show more

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Cited by 15 publications
(5 citation statements)
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“…The double system of aluminium and lead does not show the formation of inter-metallic compounds that allow for permanent connections (Figure 1) [27,28]. The same applies to the Al-Sn double system (Figure 2) [27,29]. Thus, as shown in the Al-Pb (Figure 1) and Al-Sn (Figure 2) diagrams, introducing aluminium into a metal bath with a lead-tin alloy at a temperature above 660 • C will cause its complete dissolution.…”
Section: Introductionmentioning
confidence: 93%
“…The double system of aluminium and lead does not show the formation of inter-metallic compounds that allow for permanent connections (Figure 1) [27,28]. The same applies to the Al-Sn double system (Figure 2) [27,29]. Thus, as shown in the Al-Pb (Figure 1) and Al-Sn (Figure 2) diagrams, introducing aluminium into a metal bath with a lead-tin alloy at a temperature above 660 • C will cause its complete dissolution.…”
Section: Introductionmentioning
confidence: 93%
“…This means that the diffusion process between Al and Sn atoms is advantageous. It has been reported that the internal diffusion of Sn atoms in the max phase satisfies both kinetic and thermodynamic factors [30].…”
Section: Preparation Of the Sacbi-xal Solder Alloysmentioning
confidence: 99%
“…By doping the MAX phases, solid solutions can be obtained in the M, A, or X positions, making it possible to have properties unique in their functionality. When Sn is added to Layer A, Ti 3 AlC 2 , the oxidation resistance at 900 • C increases by 33% [108]. Due to the possibility of forming solid solutions, an infinite number of non-stoichiometric MXenes can be synthesized [109].…”
Section: Propertiesmentioning
confidence: 99%